Estimation of Nonisothermal Kinetic Parameters from Tg Curve at Any Temperature and Some Aspects of Tg Analysis Related to Interaisokinetic Effect
نویسنده
چکیده
A method has been suggested for the estimation of nonisothermal kinetic parameters from TG curve at any temperature. This would help to resole reactions from a single thermogram. Some methods have been suggested to calculate nonisothermal kinetic parameters for some reactions. Intreraisokinetic or intrakinetic compensation effect technique is employed to resolve reactions. Calcium oxalate decomposition involves two consecutive reactions each of first order. Polycarbonate shows two simultaneous reaction of first order other second order while nickel and cobalt sulphate show single step fractional order reactions. HIPS and PS show single step first order reactions. HIPS and PS show single step fractional order.
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تاریخ انتشار 2013